Analysis data for probe Skepinone-L and control FM-743
Skepinone-L
| 1H NMR (200 MHz; DMSO-d6) | δ in ppm: 3.32 (s, 4 H, −CH2−CH2−), 3.40−3.46 (m, 2 H, −C1/3 propoxy−H), 3.77−4.05 (m, 3 H, C1//2/3 propoxy−H), 4.66 (t, 1 H, J = 5.7 Hz, −OH), 4.94 (d, 1 H, J = 4.9 Hz, −OH), 6.60 (s, 1 H, C1− H), 6.73 (d, 1 H, J = 8.9 Hz, C3−H), 7.01−7.10 (m, 2 H, C3′−H, C6′− H), 7.22 (d, 1 H, J = 8.3 Hz, C4′−H), 7.30−7.47 (m, 3 H, C6−H, C8− H, C9−H), 7.94 (d, 1 H, J = 8.8 Hz, C4−H), 8.54 (s, 1 H, −NH−) |
| 13C-NMR (50 MHz, DMSO-d6) | δ in ppm: 33.6 (C11), 36.3 (C10), 63.1 CC3 propoxy), 70.2 (C1 propoxy), 70.3 (C2 propoxy), 105.3 (dd, 1 C, J1 = 24.1 Hz, J2 = 27.0 Hz, C3′), 112.2 (dd, 1 C, J1 = 3.8 Hz, J2 = 22.5 Hz, C5′), 112.6 (C6), 113.8 (C3), 115.4 (C1), 119.1 (C8), 125.3 (dd, 1 C, J1 = 3.4 Hz, J2 = 11.9 Hz, C1′), 126.4 (dd, 1 C, J1 = 3.1 Hz, J2 = 9.8 Hz, C6′), 127.7 (C4a), 130.6 (C9), 133.8 (C5a), 134.6 (C4), 139.9 (C9a), 145.7 (C11a), 149.4 (C2), 156.0 (dd, 1 C, J1 = 12.6 Hz, J2 = 248.5 Hz, C4′), 157.6 (C7), 158.8 (dd, 1 C, J1 = 12.3 Hz, J2 = 243.8 Hz, C2′), 190.8 (C5) |